Micro-kinetic model of electrochemical carbon dioxide reduction over platinum in non-aqueous solvents
文献情報
Brian A. Rohr, Aayush R. Singh, Joseph A. Gauthier, Michael J. Statt, Jens K. Nørskov
The competition between the hydrogen evolution reaction and the electrochemical reduction of carbon dioxide to multi-carbon products is a well-known challenge. In this study, we present a simple micro-kinetic model of these competing reactions over a platinum catalyst under a strong reducing potential at varying proton concentrations in a non-aqueous solvent. The model provides some insight into the mechanism of reaction and suggests that low proton concentration and a high fraction of stepped sites is likely to improve selectivity to multi-carbon products.
関連文献
Engineering the outcome of cofermentation processes by altering the feedstock sugar-to-protein ratio
R. Bevilacqua, M. Mauricio-Iglesias, S. Balboa, J. M. Lema, M. Carballa
DOI: 10.1039/D2EW00144F
Magnetic properties of charge-transfer complexes based on TEMPO radicals
DOI: 10.1039/A606293H
C–H bond chlorination using nickel(ii) complexes of tetradentate amido-quinoline ligands
Sanjay Adhikari, Aniruddha Sarkar, Basab Bijayi Dhar
DOI: 10.1039/D2CC00639A
Formation mechanism of twinned β-form anhydrous guanine platelets in scallop eyes
Dongmei Guo, Yiqun Liu, Xiubin Hou, Xubo Wang, Chenge Fan, Lixia Bao, Xinpeng He, Hongmei Zhang, Yurong Ma
DOI: 10.1039/D3CE00485F
Dinuclear osmium complexes as mitochondrion-targeting antitumor photothermal agents in vivo
Meng-Fan Wang, Yu-Ang Deng, Qing-Fang Li, Shi-Jie Tang, Rong Yang, Run-Yu Zhao, Fu-Dan Liu, Xiaoxia Ren, Dan Zhang, Feng Gao
DOI: 10.1039/D2CC05230J
Temperature driven charge transfer process in quantum confined two-dimensional Mn-doped CsPbBr3 perovskite nanoplatelets
Kaliyamoorthy Justice Babu, Ayushi Shukla, Gurpreet Kaur, Arshdeep Kaur, Himanshu Bhatt
DOI: 10.1039/D2CC05142G
CNT-based bifacial perovskite solar cells toward highly efficient 4-terminal tandem photovoltaics
Min Chen, Fan Fu, Hongwei Zhu, Thomas Feurer, Wenming Tian, Chao Zhu, Ke Zhou, Shengye Jin, Shaik Mohammed Zakeeruddin, Ayodhya N. Tiwari, Nitin P. Padture, Michael Grätzel, Yantao Shi
DOI: 10.1039/D1EE04008A
こちらもおすすめ
「邻羟基阿托伐他汀内酯标准品」に適用される法規ガイドelinesは何ですか?
CAS番号163217-74-1の「邻羟基阿托伐他汀内酯标准品」は、GHS分類では危険物に分類されず、主にREACH規則とFDA/EPAの管理対象となります。R...
メチル(3R)-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩の主な用途は何ですか?
メチル(3R)-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩は、医薬品や合成化学の研究に広く用いられます。また、特定の薬物の前...
トランス-4-メチルピロリジン-3-オール塩酸塩はどのように合成されますか?
トランス-4-メチルピロリジン-3-オール塩酸塩は、4-メチルピロリジンの塩酸塩化によって合成されます。一般的な合成方法では、4-メチルピロリジンを塩酸に加えて...
硫雜環丁烷-1,1-二氧化物は安全ですか?
硫雜環丁烷-1,1-二氧化物は安全ではありません。毒性は報告されていませんが、高温下で分解し、可燃性があるため、高圧ガスは注意が必要です。密閉した容器で保管し、...
9-ヒドロキシエリプチシネ塩酸塩はどのように合成されますか?
9-ヒドロキシエリプチシネ塩酸塩は、エリプチシネから塩酸を添加することで合成されます。選択性は高いですが、収率は約70%です。
5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮の物理化学的性質は何ですか?
5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮のCAS番号は5621-86-3です。この化合物は白色の結晶性粉末で、分子量は415.03で...
1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪はどのように保存すればよいですか?
1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪は、直射日光を避けて暗所に、室温(15-25℃)で保管し、密閉容器に入れることで安定性を保つことができます。
2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンの主な用途は何ですか?
2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンは、医薬品の合成、有機合成化学、および新材料の研究で使用され...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure [(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure](https://static.chemtradehub.com/structs/100/100431-55-8-7104.webp)


