Cd2+ coordination: an efficient structuring switch for polypeptide polymers

文献情報

出版日 2018-06-13

DOI 10.1039/C8PY00810H

インパクトファクター 5.582

著者

原文を見る

要旨

Stimuli-responsive polypeptides have practical applications in devices and therapeutic delivery. Here we report that coordination to Cd2+ metal species can be used as a robust stimulus to control both, α-helix and β-sheet secondary structuring of polypeptide polymers whose metal responsiveness was achieved in the presence of a competitive buffer. As evidenced by circular dichroism analyses, secondary structuring can be easily reversed using “sequestering” external ligands, such as EDTA, that are widely used in industry, to finally design a multivalent polypeptide backbone combining metal responsiveness to two other stimuli, pH and redox conditions.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Cd2+ coordination: an efficient structuring switch for polypeptide polymers

文献情報

おすすめジャーナル

関連文献

MOF/COF hybrids as next generation materials for energy and biomedical applications

A rotatable cathode with tunable steric hindrance for high-performance aluminum organic batteries

Performance enhancement of a self-biased n-ZnO microwire/p-GaN heterojunction ultraviolet photodetector incorporating Ag nanowires

Hydrophosphinylation of unactivated alkenes with secondary phosphineoxides under visible-light photocatalysis

Correction: Activity-based NIR fluorescent probes based on the versatile hemicyanine scaffold: design strategy, biomedical applications, and outlook

Co-doped MoS2 nanosheet: a stable and pH-universal electrocatalyst for an efficient hydrogen evolution reaction

Characterization, synthesis and catalysis of hydrotalcite-related materials for highly efficient materials transformations

Correction: Crystal growth of two-dimensional organic–inorganic hybrid perovskites and their application in photovoltaics

Tuning the photophysical properties of luminescent lanthanide complexes through regioselective antenna fluorination

Encapsulation of N-containing compounds in a new hydrophilic Cd-based crystalline sponge via coordinative alignment method

こちらもおすすめ

除水剤ALT-201は安全ですか？

「邻羟基阿托伐他汀内酯标准品」に適用される法規ガイドelinesは何ですか？

メチル（3R）-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩の主な用途は何ですか？

トランス-4-メチルピロリジン-3-オール塩酸塩はどのように合成されますか？

硫雜環丁烷-1,1-二氧化物は安全ですか？

ブラエリリンの主な用途は何ですか？

9-ヒドロキシエリプチシネ塩酸塩はどのように合成されますか？

5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮の物理化学的性質は何ですか？

1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪はどのように保存すればよいですか？

2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンの主な用途は何ですか？

掲載誌

Polymer Chemistry

おすすめ化合物

Methyl 2-hydroxydodecanoate

Xylometazoline EP Impurity F

ent-Lurasidone Hydrochloride

(2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide

1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile

おすすめサプライヤー