Cu(i)-Catalyzed amidation/imidation of N-arylglycine ester derivatives via C–N coupling under mild conditions

文献情報

出版日 2017-11-22

DOI 10.1039/C7QO00851A

インパクトファクター 5.281

著者

Ramana V. Daggupati, Chandrasekharam Malapaka

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要旨

A mild and efficient reaction protocol for the cross-dehydrogenative carbon–nitrogen (CDCN) coupling of N-arylglycine ester derivatives with benzamides, aromatic heterocyclic amides (oxindole, isatins), acyclic and cyclic amides (lactams) and imides (phthalimide, succinimide) has been achieved. The copper-catalyzed C–N coupling reaction exhibits a wide substrate scope with respect to N-arylglycine ester derivatives. The ligand/oxidant free reaction facilitates the direct formation of a C(sp3)–N bond with high atom economy to furnish the corresponding amidated/imidated N-arylglycine ester derivatives in good to excellent yields under open flask conditions.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Cu(i)-Catalyzed amidation/imidation of N-arylglycine ester derivatives via C–N coupling under mild conditions

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