Facile synthesis of carbo- and heterocycles via Fe(iii)-catalyzed alkene hydrofunctionalization

文献情報

出版日 2017-10-10

DOI 10.1039/C7QO00817A

インパクトファクター 5.281

著者

Jifeng Qi, Jing Zheng, Sunliang Cui

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要旨

A facile synthesis of carbo- and heterocycles via Fe(III)-catalyzed alkene hydrofunctionalization has been developed. Various alkenes bearing a leaving group could convert to alkyl radicals through hydrogen atom transfer (HAT), and then serve as cyclization dipoles for accessing carbo- and heterocycles. The synthetic utility was further demonstrated by the synthesis of tetracyclic carbocycles from isopregol.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Facile synthesis of carbo- and heterocycles via Fe(iii)-catalyzed alkene hydrofunctionalization

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