1,2,3-Triazole-assisted C–H amidation by cobalt(iii) catalysis

文献情報

出版日 2017-08-10

DOI 10.1039/C7QO00556C

インパクトファクター 5.281

著者

Xinling Yu, Qiang Ma, Songyang Lv, Jue Li, Chen Zhang, Li Hai, Qiantao Wang, Yong Wu

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要旨

A procedure for the [Cp*CoIII]-catalyzed, 1,2,3-triazole directed C–H amidation of arenes, using dioxazolone as an efficient amidating reagent, has been developed. This reaction provides a step- and atom-economical protocol for C–N bond formation, releasing carbon dioxide as a single byproduct. Yet a variety of functional groups are well tolerated, obtaining the desired products in moderate to excellent yields.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

1,2,3-Triazole-assisted C–H amidation by cobalt(iii) catalysis

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