Silver-mediated fluorination of alkyl iodides with TMSCF3 as the fluorinating agent

文献情報

出版日 2017-06-27

DOI 10.1039/C7QO00450H

インパクトファクター 5.281

著者

Liyan Wang, Xiaohuan Jiang, Pingping Tang

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要旨

The first example of a silver-mediated fluorination of alkyl iodides with the Ruppert–Prakash reagent (TMSCF3) as a fluorinating agent has been reported. This reaction is compatible with a variety of functional groups and proceeds under mild reaction conditions. Moreover, we demonstrate that the large surface area of CaF2 dramatically increased the reaction yield.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Silver-mediated fluorination of alkyl iodides with TMSCF3 as the fluorinating agent

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