Iridium-catalyzed direct asymmetric reductive amination of aromatic ketones

文献情報

出版日 2017-06-28

DOI 10.1039/C7QO00400A

インパクトファクター 5.281

著者

Haizhou Huang, Zitong Wu, Guorui Gao, Le Zhou, Mingxin Chang

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要旨

The highly efficient direct catalytic reductive amination of aromatic ketones with diphenylmethanamine is described. Catalyzed by the iridium–monodentate phosphoramidite complex and assisted using additives, this concise and practical route provided chiral amines in high yields and with high enantioselectivity (ee values of up to 99%).

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Iridium-catalyzed direct asymmetric reductive amination of aromatic ketones

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