Copper(ii) catalyzed domino synthesis of quinoline derivatives from arylamines and alkynes

文献情報

出版日 2017-07-04

DOI 10.1039/C7QO00333A

インパクトファクター 5.281

著者

Huimin Dai, Chun-Xiao Li, Chao Yu, Zihao Wang, Hong Yan, Changsheng Lu

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要旨

The Cu(OAc)2·H2O catalyzed domino reaction of primary arylamines and electron-deficient terminal alkynes was developed at room temperature. It provides a convenient access to a variety of 2,4-disubstituted quinolines in good to excellent yields without protection from moisture or air. Control experiments suggest that the reaction might be initiated from alkyne homocoupling, followed by copper catalyzed hydroamination and cyclization.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Copper(ii) catalyzed domino synthesis of quinoline derivatives from arylamines and alkynes

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