Precise syntheses of structurally possible all tetrablock quaterpolymers by a methodology combining living anionic polymerization with linking chemistry using 1 : 1 addition reaction

文献情報

出版日 2017-12-14

DOI 10.1039/C7PY01948C

インパクトファクター 5.582

著者

Yuri Matsuo

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要旨

A methodology combining living anionic polymerization with linking chemistry using 1 : 1 addition reaction has been developed for the syntheses of tetrablock quaterpolymers composed of A, B, C, and D blocks. With this methodology using the ω-chain-end-(α-phenylacrylate (PA))-functionalized D, α,ω-chain-end-(2-tetrahydropyranyl ether and PA)-functionalized D, and ω-chain-end-PA-functionalized AD as the building blocks, the following all structurally possible twelve tetrablock quaterpolymers were successfully synthesized: ABCD, ABDC, ACBD, ACDB, ADBC, ADCB, BACD, BADC, BCAD, BDAC, CABD, and CBAD. Polystyrene, poly(2-vinylpyridine), poly(tert-butyl methacrylate) (or poly(methyl methacrylate)), and poly(1,2-butylene oxide) prepared by living anionic polymerization were used as A, B, C, and D blocks, respectively. The polymers synthesized in this study are quite new tetrablock quaterpolymers and well-defined in structure.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Precise syntheses of structurally possible all tetrablock quaterpolymers by a methodology combining living anionic polymerization with linking chemistry using 1 : 1 addition reaction

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