Aziridine-functionalized polydimethylsiloxanes for tailorable polymeric scaffolds: aziridine as a clickable moiety for structural modification of materials

文献情報

出版日 2017-03-15

DOI 10.1039/C7PY00317J

インパクトファクター 5.582

著者

Hyun Kyung Moon, Seohyun Kang, Hyo Jae Yoon

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要旨

This paper shows that tailorable polymeric scaffolds on a molecular scale could be achieved through the ring opening reaction of a three-membered N-heterocyclic compound, aziridine. Aziridine is incorporated into an elastomeric polymer backbone (here, PDMS) through Pt(0)-catalyzed hydrosilylation, retaining attractive features such as optical transparency and elastic properties compared to conventional PDMS. The resulting aziridine-containing PDMS is chemoselectively and regio-specifically post-modified through an orthogonal ring opening reaction of the aziridine and takes advantage of the wide substrate scope of aziridine chemistry.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Aziridine-functionalized polydimethylsiloxanes for tailorable polymeric scaffolds: aziridine as a clickable moiety for structural modification of materials

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