A highly active chiral (S,S)-bis(oxazoline) Pd(ii) alkyl complex/activator catalytic system for vinyl polymerization of norbornene in air and water

文献情報

出版日 2016-12-26

DOI 10.1039/C6PY01859A

インパクトファクター 5.582

著者

Yingda Huang, Jianyun He, Zhanxiong Liu, Guilong Cai, Shaowen Zhang, Xiaofang Li

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要旨

A series of air/water-tolerant chiral Pd alkyl complexes (R2-(S,S)-BOZ)PdR′ (1–3, R = CH(CH3)2, Ph; R′ = Me, Ph) were synthesized and structurally characterized. In the presence of an excess of activator, such as [Ph3C][B(C6F5)4], [PhMe2NH][B(C6F5)4], or B(C6F5)3, the air/water-tolerant chiral Pd(II) alkyl complexes 1–3 could promote the norbornene polymerization in air and water using unpretreated technical grade solvent and monomer with extremely high activity up to 1.7 × 109 g PNB per molPd per h.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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A highly active chiral (S,S)-bis(oxazoline) Pd(ii) alkyl complex/activator catalytic system for vinyl polymerization of norbornene in air and water

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Polymer Chemistry

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