Anti-site mixing governs the electrochemical performances of olivine-type MgMnSiO4 cathodes for rechargeable magnesium batteries
文献情報
Takuya Mori, Titus Masese, Yuki Orikasa, Zhen-Dong Huang, Tetsuya Okado, Jungeun Kim, Yoshiharu Uchimoto
Rechargeable magnesium batteries are deemed as the next-generation secondary battery systems because of their high theoretical capacity and the terrestrial abundance of magnesium, which is used as the anode in these batteries. The cathode material is an important factor to improve the energy density of the magnesium batteries. In this study, we investigate olivine-type MgMnSiO4 cathode materials owing to their high theoretical capacity (>300 mA h g−1). The low-temperature synthesis of MgMnSiO4 suppresses anti-site mixing between Mg and Mn, which drastically improves the charge–discharge capacities of the magnesium battery cathode. Our results show that the suppression of the degree of anti-site mixing between Mg and Mn enhances the diffusion of Mg2+ during magnesium (de)insertion, and therefore, it is a dominant factor that affects the electrochemical performance of olivine-type MgMnSiO4.
おすすめジャーナル

Nature Medicine

Drug Discovery Today

Saudi Pharmaceutical Journal

Russian Journal of Applied Chemistry

Russian Chemical Bulletin

Chemical Communications

Russian Journal of Bioorganic Chemistry

Journal of Saudi Chemical Society

Organic Process Research & Development

Current Opinion in Colloid & Interface Science
関連文献
Photodissociation of p-ethyl- and p-(α-hydroxyethyl)toluene in solution
M. Fujiwara, K. Mishima
DOI: 10.1039/B004079G
Chirality and intermolecular forces: studies using R2PI experiments in supersonic beams
S. Piccirillo, T. M. Di Palma, M. Speranza
DOI: 10.1039/B004138F
Analysis of gas dissociation rate into liquid phase under magnetic field gradient
Akifumi Yamada
DOI: 10.1039/B003472J
Magneto-optic measurements of spectral holes in metallo-porphyrin derivatives in polymer matrices
Robin Purchase, Matt Sellars, Elmars Krausz, Neil Manson
DOI: 10.1039/B003851M
51V magic angle spinning solid state NMR studies of Bi4V2O11 in oxidized and reduced states
F. Delmaire, M. Rigole, E. A. Zhilinskaya, A. Aboukaïs, R. Hubaut, G. Mairesse
DOI: 10.1039/B003644G
Mesoscopic models of nucleation and growth processes: a challenge to experiment
DOI: 10.1039/A809348B
Polytriphenylamine derivatives as materials for hole transporting layers in electroluminescent devices
DOI: 10.1039/A808613C
Adsorption of CO2 on FSM-type mesoporous silicas
Masahiro Katoh, Keiichi Sakamoto, Mituo Kamiyamane, Tahei Tomida
DOI: 10.1039/B004505P
こちらもおすすめ
「邻羟基阿托伐他汀内酯标准品」に適用される法規ガイドelinesは何ですか?
CAS番号163217-74-1の「邻羟基阿托伐他汀内酯标准品」は、GHS分類では危険物に分類されず、主にREACH規則とFDA/EPAの管理対象となります。R...
メチル(3R)-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩の主な用途は何ですか?
メチル(3R)-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩は、医薬品や合成化学の研究に広く用いられます。また、特定の薬物の前...
トランス-4-メチルピロリジン-3-オール塩酸塩はどのように合成されますか?
トランス-4-メチルピロリジン-3-オール塩酸塩は、4-メチルピロリジンの塩酸塩化によって合成されます。一般的な合成方法では、4-メチルピロリジンを塩酸に加えて...
硫雜環丁烷-1,1-二氧化物は安全ですか?
硫雜環丁烷-1,1-二氧化物は安全ではありません。毒性は報告されていませんが、高温下で分解し、可燃性があるため、高圧ガスは注意が必要です。密閉した容器で保管し、...
9-ヒドロキシエリプチシネ塩酸塩はどのように合成されますか?
9-ヒドロキシエリプチシネ塩酸塩は、エリプチシネから塩酸を添加することで合成されます。選択性は高いですが、収率は約70%です。
5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮の物理化学的性質は何ですか?
5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮のCAS番号は5621-86-3です。この化合物は白色の結晶性粉末で、分子量は415.03で...
1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪はどのように保存すればよいですか?
1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪は、直射日光を避けて暗所に、室温(15-25℃)で保管し、密閉容器に入れることで安定性を保つことができます。
2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンの主な用途は何ですか?
2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンは、医薬品の合成、有機合成化学、および新材料の研究で使用され...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




