Post-polymerization modification of poly(vinyl ether)s: a Ru-catalyzed oxidative synthesis of poly(vinyl ester)s and poly(propenyl ester)s

文献情報

出版日 2015-10-20

DOI 10.1039/C5PY01409C

インパクトファクター 5.582

著者

Di Liu

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要旨

Poly(vinyl ester)s were readily prepared via a ruthenium catalyzed C–H oxidation of the corresponding poly(vinyl ether)s under mild conditions. The transformations were efficient and in many cases proceeded without significant chain cleavage. The method was also successfully used to prepare high molecular weight poly(propenyl ester) for the first time as well as a polyester with a relatively high content (>50%) of γ-butyrolactone repeat unit from poly(tetrahydrofuran). The polymeric products were characterized via FT-IR spectroscopy, NMR spectroscopy, gel permeation chromatography, and other techniques.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Post-polymerization modification of poly(vinyl ether)s: a Ru-catalyzed oxidative synthesis of poly(vinyl ester)s and poly(propenyl ester)s

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