Synthesis of cardo-polymers using Tröger's base formation

文献情報

出版日 2014-06-20

DOI 10.1039/C4PY00607K

インパクトファクター 5.582

著者

Mariolino Carta, Matthew Croad, Johannes C. Jansen, Paola Bernardo, Gabriele Clarizia, Neil B. McKeown

原文を見る

要旨

A series of novel cardo-polymers was prepared using a polymerisation reaction based on Tröger's base formation. The precursor dianiline monomers are readily available from the reactions between appropriate anilines and cyclic ketones. One adamantyl-based cardo-polymer displays intrinsic microporosity with an apparent BET surface area of 615 m2 g−1. This polymer demonstrates a combination of good solubility and high molecular mass facilitating the solvent casting of robust films suitable for gas permeability measurements. The intrinsic microporosity of the polymer provides high gas permeabilities and moderate selectivities with particular promise for gas separations involving hydrogen.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Synthesis of cardo-polymers using Tröger's base formation

文献情報

おすすめジャーナル

関連文献

Investigation of glycerol hydrogen-bonding networks in choline chloride/glycerol eutectic-forming liquids using neutron diffraction

Effects of temperature on the thermal conductivity of amorphous CaO–SiO2–Al2O3 slags: a computational insight

The mechanism of thiophene oxidation on metal-free two-dimensional hexagonal boron nitride

Magnon-driven interfacial magnetoelectric coupling in Co/PMN-PT multiferroic heterostructures

The tetracapped truncated tetrahedron in 16-vertex tetrametallaborane structures: spherical aromaticity with an isocloso rather than a closo skeletal electron count

Front cover

Embedding of atoms into the nanopore sites of the C6N6 and C6N8 porous carbon nitride monolayers with tunable electronic properties

When is the Bell–Evans–Polanyi principle fulfilled in Diels–Alder reactions of fullerenes?

Charge separation, recombination and intersystem crossing of directly connected perylenemonoimide–carbazole electron donor/acceptor dyads

Thermal decomposition of mixed calcium oxalate hydrates – kinetic deconvolution of complex heterogeneous processes

こちらもおすすめ

除水剤ALT-201は安全ですか？

「邻羟基阿托伐他汀内酯标准品」に適用される法規ガイドelinesは何ですか？

メチル（3R）-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩の主な用途は何ですか？

トランス-4-メチルピロリジン-3-オール塩酸塩はどのように合成されますか？

硫雜環丁烷-1,1-二氧化物は安全ですか？

ブラエリリンの主な用途は何ですか？

9-ヒドロキシエリプチシネ塩酸塩はどのように合成されますか？

5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮の物理化学的性質は何ですか？

1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪はどのように保存すればよいですか？

2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンの主な用途は何ですか？

掲載誌

Polymer Chemistry

おすすめ化合物

2-Fluoro-4-(3-methylphenyl)benzoic acid

6-Bromo-3,4-dihydro-2H-1,4-benzoxazine hydrochloride (1:1)

{[3-(Hexadecyloxy)propoxy](hydroxy)phosphoryl}methyl 4-methylbenzenesulfonate

ent-Lurasidone Hydrochloride

6-(2-Methylphenyl)-2-pyridinecarboxylic acid

おすすめサプライヤー