Absolut “copper catalyzation perfected”; robust living polymerization of NIPAM: Guinness is good for SET-LRP

文献情報

出版日 2013-09-11

DOI 10.1039/C3PY01075A

インパクトファクター 5.582

著者

Christopher Waldron, Qiang Zhang, Zaidong Li, Vasiliki Nikolaou, Gabit Nurumbetov, Jamie Godfrey, Ronan McHale, Gokhan Yilmaz, Rajan K. Randev, Mony Girault, Kayleigh McEwan, David M. Haddleton, Martijn Droesbeke, Alice J. Haddleton, Paul Wilson, Alexandre Simula, Jennifer Collins, Danielle J. Lloyd, James A. Burns, Christopher Summers, Claudia Houben, Athina Anastasaki, Muxiu Li, C. Remzi Becer, Jenny K. Kiviaho, Nuttapol Risangud

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要旨

The controlled polymerization of N-isopropyl acrylamide (NIPAM) is reported in a range of international beers, wine, ciders and spirits utilizing Cu(0)-mediated living radical polymerization (SET-LRP). Highly active Cu(0) is first formed in situ by the rapid disproportionation of [Cu(I)(Me6-Tren)Br] in the commercial water–alcohol mixtures. Rapid, yet highly controlled, radical polymerization follows (Đ values as low as 1.05) despite the numerous chemicals of diverse functionality present in these solvents e.g. alpha acids, sugars, phenols, terpenoids, flavonoids, tannins, metallo-complexes, anethole etc. The results herein demonstrate the robust nature of the aqueous SET-LRP protocol, underlining its ability to operate efficiently in a wide range of complex chemical environments.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Absolut “copper catalyzation perfected”; robust living polymerization of NIPAM: Guinness is good for SET-LRP

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Polymer Chemistry

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