Synthesis of novel trithiocarbonate and allyl sulfide containing monomers

文献情報

出版日 2013-08-14

DOI 10.1039/C3PY00709J

インパクトファクター 5.582

著者

Christopher R. Fenoli

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要旨

In this study, we present a mild, efficient, and high yield synthesis of a variety of trithiocarbonates and allyl sulphide-containing AFT (addition–fragmentation termination) monomers containing terminal (meth)acrylate functional groups. The trithiocarbonate moiety core was synthesized with reaction yields often above 95%. Synthesis of monomers with allyl sulphide cores gave yields ranging from 48–92%. These monomers, designated as CRAFT (Controllable Reversible Addition Chain Transfer) monomers, offer the ability to control the mechanical and polymerization properties of the resulting thiol-Michael and chain-growth polymer networks in a previously unattainable manner. The triothiocarbonates reached 70–81% acrylate conversion in 10–200 s of light exposure while the allyl sulphide monomers reached 74–85% conversion in 10–50 s.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Synthesis of novel trithiocarbonate and allyl sulfide containing monomers

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